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A Mixed‐Valence Mixed‐Spin Prussian‐Blue‐Like Heptanuclear Complex
Author(s) -
Rogez Guillaume,
Marvilliers Arnaud,
Rivière Eric,
Audière JeanPaul,
Lloret Francesc,
Varret François,
Goujon Antoine,
Mendenez Nieves,
Girerd JeanJacques,
Mallah Talal
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000818)39:16<2885::aid-anie2885>3.0.co;2-4
Subject(s) - prussian blue , ferromagnetism , valence (chemistry) , condensed matter physics , ground state , spin (aerodynamics) , materials science , coupling (piping) , electronic structure , physics , quantum mechanics , electrode , metallurgy , electrochemistry , thermodynamics
A high‐spin ground state S >8 is obtained through ferromagnetic coupling in a Fe II Fe complex that models the electronic properties of Prussian blue. The picture shows the postulated core structure for this heptanuclear complex.