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Remarkable In / out Inversions at Bridgehead Phosphorus Atoms
Author(s) -
Alder Roger W.,
Read David
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000818)39:16<2879::aid-anie2879>3.0.co;2-j
Subject(s) - borohydride , chemistry , trapping , ion , phosphorus , inversion (geology) , substitution reaction , computational chemistry , photochemistry , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , geology , ecology , paleontology , structural basin , biology
Inversion at the leaving group in a substitution reaction is implied in the reaction of 1 with borohydride at room temperature. The trapping of 2 leads to 3 , even though the stable monoprotonated ion is 4 .