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(2,6‐Mes 2 H 3 C 6 ) 2 BiH, a Stable, Molecular Hydride of a Main Group Element of the Sixth Period, and Its Conversion to the Dibismuthene (2,6‐Mes 2 H 3 C 6 )BiBi(2,6‐Mes 2 C 6 H 3 )
Author(s) -
Hardman Ned J.,
Twamley Brendan,
Power Philip P.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000804)39:15<2771::aid-anie2771>3.0.co;2-7
Subject(s) - hydride , period (music) , main group element , group (periodic table) , chloride , element (criminal law) , chemistry , materials science , organic chemistry , transition metal , physics , metal , catalysis , political science , acoustics , law
The first stable organic hydride of a main group element of the sixth period ( 1 ) has been prepared by the simple reduction of the corresponding chloride precursor. Interestingly, compound 1 transforms into the dibismuthene 2 when heated [Eq. (1)].