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A New Kinetic Template Synthesis of Triphosphacyclodecanes
Author(s) -
Edwards Peter G.,
Newman Paul D.,
Hibbs David E.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000804)39:15<2722::aid-anie2722>3.0.co;2-b
Subject(s) - azobisisobutyronitrile , chemistry , kinetic energy , stereochemistry , combinatorial chemistry , organic chemistry , physics , quantum mechanics , polymerization , polymer
The radical‐induced cyclization of 1,2‐bis(phosphanyl)ethane and diallylphenylphosphane coordinated to a (pentamethylcyclopentadienyl)iron( II ) template gives the first ten‐membered triphosphorus macrocycle with three inequivalent phosphorus centers [Eq. (1); AIBN=azobisisobutyronitrile].