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Aluminum Fluoride as a Storage Matrix for Atomic Hydrogen
Author(s) -
Scholz Gudrun,
Stößer Reinhard,
Momand Jan Alam,
Zehl Andrea,
Klein Jeannette
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000717)39:14<2516::aid-anie2516>3.0.co;2-y
Subject(s) - hydrogen fluoride , fluoride , hydrogen , hydrogen storage , matrix (chemical analysis) , aluminium , hydrogen atom , atom (system on chip) , trapping , atomic physics , materials science , chemistry , crystallography , group (periodic table) , chemical physics , inorganic chemistry , metallurgy , physics , composite material , organic chemistry , ecology , computer science , biology , embedded system
A long‐term trapping of atomic hydrogen in a fluoride of a 3rd main group element has been demonstrated at temperatures above room temperature. The H . atoms are shown to be sensitive and minimally disruptive spin probes for the structural reorganization and dynamics of the fluoride matrix (see picture for an H . atom trapped inside an F cage in α ‐AlF 3 ).