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Fixation of Dinitrogen to a Mesoscale Solid Salt Using a Titanium Oxide/Conducting Polymer System
Author(s) -
Hoshino Katsuyoshi,
Inui Masaki,
Kitamura Takashi,
Kokado Hiroshi
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000717)39:14<2509::aid-anie2509>3.0.co;2-i
Subject(s) - polythiophene , ammonium perchlorate , oxide , titanium , salt (chemistry) , conductive polymer , polymer , inorganic chemistry , titanium oxide , materials science , mesoscale meteorology , chemistry , ammonium , photochemistry , chemical engineering , polymer chemistry , organic chemistry , catalysis , engineering , geology , climatology
Under conditions milder than the Haber process , dinitrogen interacts with a titanium oxide/conductive polythiophene system and is fixed into growing mesoscale needles of ammonium perchlorate (see picture, scale bar 10 μm) upon irradiation with white light.