Premium
Inorganic–Organic Hybrid Materials Constructed from [(VO 2 )(HPO 4 )] ∞ Helical Chains and [M(4,4′‐bpy) 2 ] 2+ (M=Co, Ni) Fragments
Author(s) -
Shi Zhan,
Feng Shouhua,
Gao Shan,
Zhang Lirong,
Yang Guoyu,
Hua Jia
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000703)39:13<2325::aid-anie2325>3.0.co;2-l
Subject(s) - crystallography , hydrothermal circulation , hybrid material , chemistry , hydrothermal synthesis , crystal structure , diffraction , hydrothermal reaction , stereochemistry , materials science , chemical engineering , organic chemistry , physics , optics , engineering
Both left‐handed and right‐handed helical chains of [(VO 2 )(HPO 4 )] ∞ , which are linked by [M(4,4′‐bpy) 2 ] to form three‐dimensional framework structures (see picture), are present in the structures of two novel inorganic–organic hybrid materials, [M(4,4′‐bpy) 2 (VO 2 ) 2 (HPO 4 ) 4 ]. These were prepared from hydrothermal systems and characterized by single‐crystal X‐ray diffraction. M=Co or Ni; bpy=bipyridine.