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Tetraphenylphosphonium Hexaazidoarsenate( V ): The First Structurally Characterized Binary As V –Azide Species
Author(s) -
Klapötke Thomas M.,
Nöth Heinrich,
Schütt Thomas,
Warchhold Marcus
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/1521-3773(20000616)39:12<2108::aid-anie2108>3.0.co;2-f
Subject(s) - azide , crystallography , symmetry (geometry) , atom (system on chip) , chemistry , ion , stereochemistry , mathematics , computer science , geometry , organic chemistry , parallel computing
A six‐fold coordinated As atom was shown to be the first structurally characterized As V azide [PPh 4 ] + [As(N 3 ) 6 ] − . The anion (see picture) has idealized S 2 symmetry.