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From High‐Spin Organic Molecules to Organic Polymers with Magnetic Ordering
Author(s) -
Rajca Andrzej
Publication year - 2002
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/1521-3765(20021104)8:21<4834::aid-chem4834>3.0.co;2-e
Subject(s) - unpaired electron , spins , polymer , organic molecules , organic polymer , conjugated system , spin (aerodynamics) , materials science , magnet , rational design , condensed matter physics , nanotechnology , molecule , chemical physics , chemistry , physics , organic chemistry , thermodynamics , composite material , quantum mechanics
This concept paper outlines the design of the first π‐conjugated organic polymer with magnetic ordering. This rational, “bottom‐up” macromolecular design is based on synthesis and study of polyarylmethyl polyradicals with increasing number of exchange‐coupled unpaired electron spins. The prospects for attaining organic polymer magnets with stability at ambient temperature and/or higher magnetic ordering temperatures will be discussed.