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Asymmetric Halogeno‐Bridged Complexes: New Reagents in Organometallic Synthesis and Catalysis
Author(s) -
Severin Kay
Publication year - 2002
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/1521-3765(20020402)8:7<1514::aid-chem1514>3.0.co;2-z
Subject(s) - bimetallic strip , halide , reagent , catalysis , homogeneous , chemistry , group 2 organometallic chemistry , organometallic chemistry , combinatorial chemistry , homogeneous catalysis , metal , nanotechnology , organic chemistry , materials science , molecule , physics , thermodynamics
Several methods to synthesize bimetallic complexes in which two different metal fragments are connected by halide bridges are described. Using simple starting materials a large pool of structurally defined bimetallic complexes with unique chemical reactivities can be prepared in short time. Applications in organometallic synthesis and homogeneous catalysis are discussed.