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(Phosphanyloxazoline)palladium Complexes, Part I: ( η 3 ‐1,3‐Dialkylallyl)(phosphanyloxazoline)palladium Complexes: X‐Ray Crystallographic Studies, NMR Investigations, and Quantum‐Chemical Calculations
Author(s) -
Kollmar Martin,
Goldfuss Bernd,
Reggelin Michael,
Rominger Frank,
Helmchen Günter
Publication year - 2001
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/1521-3765(20011119)7:22<4913::aid-chem4913>3.0.co;2-7
Subject(s) - palladium , quantum chemical , density functional theory , chemistry , x ray , crystallography , nuclear magnetic resonance spectroscopy , chemical shift , crystal structure , molecule , computational chemistry , stereochemistry , organic chemistry , catalysis , physics , quantum mechanics
A series of systematically varied ( η 3 ‐1,3‐dialkylallyl)palladium complexes of (4 S )‐[2‐(2‐diphenylphosphanyl)phenyl]‐4,5‐dihydrooxazole (PHOX) ligands were characterized by X‐ray crystal structure analysis and NMR spectroscopy. Complexes with identical substituents in the 1,3‐positions of the allyl group can form eight stereoisomers. In solution four to six isomers were observed and their conformations assigned with the aid of NOE experiments. The dynamic behavior of the complexes was analyzed. In addition, quantum‐chemical calculations (restricted Hartree–Fock (HF), density functional theory (DFT)) were carried out and gave satisfactory agreement with experimental findings.