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Programmed Construction of Discrete Self‐Assembled Cyclic Aggregates
Author(s) -
Mazik Monika,
Bläser Dieter,
Boese Roland
Publication year - 2000
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/1521-3765(20000804)6:15<2865::aid-chem2865>3.0.co;2-y
Subject(s) - chemistry , hydrogen bond , molecule , pyridine , stereochemistry , solid state , crystallography , medicinal chemistry , organic chemistry
Examples for programmed self‐assembly of α , β ‐unsaturated ketoximes carrying a terminal pyridine subunit are described. The solid‐state structures of a series of pyridinyl α , β ‐unsaturated ketoximes 1 were investigated by X‐ray structural analysis; this demonstrated that molecules 3 ‐ 5 predictably form discrete cyclic aggregates stabilized by a network of hydrogen bonds and aromatic interactions.