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Reaction of “[Mn II (CH 2 t Bu) 2 ]” with Bidentate Diimine Ligands: From Simple Base Adducts to CC Activation of the Ligand
Author(s) -
Riollet Virginie,
Copéret Christophe,
Basset JeanMarie,
Rousset Laurence,
Bouchu Denis,
Grosvalet Laurent,
Perrin Monique
Publication year - 2002
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/1521-3757(20020816)114:16<3151::aid-ange3151>3.0.co;2-l
Subject(s) - denticity , diimine , chemistry , ligand (biochemistry) , adduct , simple (philosophy) , base (topology) , medicinal chemistry , crystallography , catalysis , crystal structure , mathematics , organic chemistry , philosophy , receptor , epistemology , mathematical analysis , biochemistry
Abhängig vom Substitutionsmuster der Diiminliganden sind die Ligandentransformationen, die bei der Komplexierung mit Mn II ‐Dialkylkomplexen eintreten. So entsteht 2 durch eine Folge von 1,3‐Wanderungen aus dem angenommenen Intermediat 1 .

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