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Mechanistic Rationale of a Palladium‐Catalyzed Allylic Substitution Polymerization—Carbon−Carbon Bond‐Forming Polycondensation out of Stoichiometric Control by Cascade Bidirectional Allylation
Author(s) -
Nomura Nobuyoshi,
Tsurugi Ko,
Okada Masahiko
Publication year - 2001
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/1521-3757(20010518)113:10<1986::aid-ange1986>3.0.co;2-u
Subject(s) - allylic rearrangement , palladium , catalysis , stoichiometry , chemistry , substitution (logic) , cascade , polymerization , carbon fibers , condensation polymer , polymer chemistry , substitution reaction , organic chemistry , combinatorial chemistry , materials science , polymer , composite number , chromatography , computer science , composite material , programming language
Die Reaktion transienter Olefin‐L n Pd 0 ‐Komplexe muss gesteuert werden, um erfolgreich über allylische Substitutionen verlaufende Polymerisationen durchzuführen. Dies enthüllt einen neuen Aspekt bei den unter C‐C‐Bindungsbildung ablaufenden Polykondensationen (siehe Schema).