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Synthesis, Characterization, and Crystal Structures of Various Energetic Urotropinium Salts with Azide, Nitrate, Dinitramide and Azotetrazolate Counter Ions
Author(s) -
Ang HowGhee,
Fraenk Wolfgang,
Karaghiosoff Konstantin,
Klapötke Thomas M.,
Nöth Heinrich,
Sprott Joanna,
Suter Max,
Vogt Martin,
Warchhold Marcus
Publication year - 2002
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200213)628:13<2901::aid-zaac2901>3.0.co;2-k
Subject(s) - chemistry , raman spectroscopy , azide , nuclear chemistry , crystallography , stereochemistry , polymer chemistry , organic chemistry , physics , optics
Urotropinium nitrate, N ‐methylurotropinium azide, dinitramide and azotetrazolate salts have been prepared and fully characterized by analytical and spectoscopic ( 1 H, 13 C, 14 N NMR, IR, Raman) methods. The structures of all four compounds have been determined using X‐ray diffraction techniques and represent new examples of the class of high energy density materials (HEDMs).