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Synthesis, Characterization, and Crystal Structures of Cu, Ag, and Pd Dinitramide Salts
Author(s) -
Ang HowGhee,
Fraenk Wolfgang,
Karaghiosoff Konstantin,
Klapötke Thomas M.,
Mayer Peter,
Nöth Heinrich,
Sprott Joanna,
Warchhold Marcus
Publication year - 2002
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200213)628:13<2894::aid-zaac2894>3.0.co;2-r
Subject(s) - raman spectroscopy , chemistry , crystallography , infrared spectroscopy , nuclear magnetic resonance spectroscopy , stereochemistry , physics , organic chemistry , optics
The literature known, but not fully characterized, silver dinitramide transfer reagents AgN(NO 2 ) 2 ( 1 ), [Ag(NCCH 3 )][N(NO 2 ) 2 ] ( 2 ), and [Ag(py) 2 ][N(NO 2 ) 2 ] ( 3 ) have been investigated by 109 Ag, 14 N NMR and vibrational spectroscopy (IR, Raman). In addition, the poorly understood [Cu(NH 3 ) 4 ][N(NO 2 ) 2 )] 2 ( 4 ) and [Pd(NH 3 ) 4 ][N(NO 2 ) 2 ] 2 , ( 5 ) have also been prepared and characterized by 14 N NMR and vibrational spectroscopy (IR, Raman). The structures of 2 — 5 have also been determined by X‐ray diffraction.