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Synthese und Kristallstruktur von [C(NMe 2 ) 3 ] 2 [(CO) 4 Fe(μ‐InCl 2 ) 2 Fe(CO) 4 ]
Author(s) -
Petz Wolfgang,
Weller Frank
Publication year - 2002
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200213)628:13<2825::aid-zaac2825>3.0.co;2-z
Subject(s) - monoclinic crystal system , octahedron , dichloromethane , pentane , crystal structure , chemistry , crystallography , ring (chemistry) , atom (system on chip) , stereochemistry , solvent , organic chemistry , computer science , embedded system
Synthesis and Crystal Structure of [C(NMe 2 ) 3 ] 2 [(CO) 4 Fe(μ‐InCl 2 ) 2 Fe(CO) 4 ] Treatment of [C(NMe 2 ) 3 ] 2 [(CO) 4 FeInCl 3 ] ( 1 ) with hot water produces the dinuclear complex [C(NMe 2 ) 3 ] 2 [(CO) 4 Fe(μ‐InCl 2 ) 2 Fe(CO) 4 ] ( 2 ) which could be crystallized from dichloromethane/pentane. 2 crystallizes in the monoclinic space group P2 1 /n with a = 835.7(1), b = 1187.8(1), c = 1902.7(1) pm, β = 91.877(5)° and Z = 2. The anion contains a four‐membered Fe—In—Fe—In ring with octahedral environment at the iron atom and tetrahedral coordination at the In atom.