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Effect of Partial Hydrolysis in Switching the Mode of Inter‐molecular Bonding between Metal Complexes
Author(s) -
Doble Dan M. J.,
Blake Alexander J.,
Hibbs David E.,
Jackson Matthew S.,
Li WanSheung,
Schröder Martin
Publication year - 2002
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200211)628:11<2311::aid-zaac2311>3.0.co;2-p
Subject(s) - chemistry , hydrolysis , carboxylate , crystallography , metal , stereochemistry , cluster (spacecraft) , intermolecular force , molecule , organic chemistry , computer science , programming language
The assembly of [Cd(L 1 )] — {[L 1 ] 3— = N[CH 2 CH 2 N=C(CH 3 )COO — ] 3 } into the tetranuclear cluster {[Cd(L 1 )]Na(H 2 O) 2 } 2 in the presence of Na + is mediated by Na + ‐carboxylate interactions; in contrast In 3+ and Fe 3+ induce the partial hydrolysis of [L 1 ] 3— to afford the complexes [In(L 2 )Cl] and {[Fe(L 2 )] 2 O} {[L 2 ] 2— = N[CH 2 CH 2 NH 2 ][CH 2 CH 2 N=C(CH 3 )COO — ] 2 } which aggregate via intermolecular H‐bonding.