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X‐Ray Crystal Structures of Hexa‐oxotellurate Complexes of Ruthenium(VI) and Silver(III): Na 6 [RuO 2 {TeO 4 (OH) 2 } 2 ]·16H 2 O and Na 5 [Ag{TeO 4 (OH) 2 } 2 ]·16H 2 O
Author(s) -
Hector Andrew L.,
Hill Nicholas J.,
Levason William,
Webster Michael
Publication year - 2002
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - Czech
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200205)628:4<815::aid-zaac815>3.0.co;2-u
Subject(s) - materials science , metallurgy , chemistry
X‐ray crystal structures are reported for Na 6 [RuO 2 {TeO 4 (OH) 2 } 2 ]·16H 2 O and Na 5 [Ag{TeO 4 (OH) 2 } 2 ]·16H 2 O which contain respectively Ru VI and Ag III coordinated to chelating bidentate tellurate ([TeO 4 (OH) 2 ] 4− ) groups. Na 6 [RuO 2 {TeO 4 (OH) 2 } 2 ]·16H 2 O: Space group P1¯, Z = 2, lattice dimensions at 120 K; a = 6.9865(1), b = 8.7196(2), c = 11.7395(2)Å, α = 74.008(1), β = 79.954(1), γ = 88.514(1)°; R1 = 0.025. Na 5 [Ag{TeO 4 (OH) 2 } 2 ]·16H 2 O: Space group P1¯, Z = 2, lattice dimensions at 120 K; a = 5.888(1), b = 8.932(1), c = 12.561(2)Å, α = 98.219(6), β = 97.964(9), γ = 93.238(14)°; R1 = 0.047.