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N,N′‐Diorganylsubstituted Hydrazinium Azides
Author(s) -
Hammerl Anton,
Holl Gerhard,
Kaiser Manfred,
Klapötke Thomas M.,
Kränzle Rainer,
Vogt Martin
Publication year - 2002
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200201)628:1<322::aid-zaac322>3.0.co;2-s
Subject(s) - azide , chemistry , elemental analysis , raman spectroscopy , infrared spectroscopy , crystal structure , medicinal chemistry , single crystal , polymer chemistry , crystallography , inorganic chemistry , organic chemistry , physics , optics
1,2‐Diorganylsubstituted derivatives of hydrazinium azide were examined in order to investigate their higher volatility and higher sensitivity to initiation compared to 1,1‐diorganylsubstituted hydrazinium azide derivatives. The compounds were synthesized from the respective hydrazines by reaction with HN 3 and characterized by elemental analysis, vibrational (IR, Raman) and multinuclear NMR spectroscopy ( 1 H, 13 C, 14 N). Their sensitivity to friction, shock, electrostatic impact and heat was examined and the explosion products were investigated. The crystal structure of pyrazolidinium azide was determined.