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[{C 8 H 12 Rh} 3 (μ 3 ‐OH) 2 ]SbF 6 : Ein neuer metallorganischer Rhodiumkomplex mit Rh 3 O 2 ‐Kern
Author(s) -
Kuhn Norbert,
Grathwohl Martin,
Nachtigal Christiane,
Steimann Manfred,
Henkel Gerald
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200109)627:9<2039::aid-zaac2039>3.0.co;2-#
Subject(s) - physics
[{C 8 H 12 Rh} 3 (μ 3 ‐OH) 2 ]SbF 6 : A New Organometallic Rhodium Complex with Rh 3 O 2 Core Crystals of C 24 H 38 F 7 O 2 Rh 3 Sb ( 3 ) obtained from the crystallisation of 2 from wet solvents consist of [{C 8 H 12 Rh} 3 (μ 3 ‐OH) 2 ] + cations connected with the SbF 6 – anions via hydrogen bonds. In the cations, the Rh 3 faces are bicapped by OH – ligands.