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Synthese und Einkristallstrukturanalyse von [M(NH 3 ) 6 ]C 60 · 6 NH 3 (M = Co 2+ , Zn 2+ )
Author(s) -
Brumm Holger,
Jansen Martin
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200107)627:7<1433::aid-zaac1433>3.0.co;2-h
Subject(s) - isostructural , liquid ammonia , crystallography , ammonia , chemistry , single crystal , crystal structure , ion , stereochemistry , organic chemistry
Synthesis and Single Crystal Structure Analysis of [M(NH 3 ) 6 ]C 60 · 6 NH 3 (M = Co 2+ , Zn 2+ ) [M(NH 3 ) 6 ]C 60 · 6 NH 3 (M = Co 2+ , Zn 2+ ) was synthesized from K 2 C 60 by ion exchange in liquid ammonia. According to single crystal structure analyses the new fullerides are isostructural to the respective Mn, Ni and Cd compounds. The deformation patterns of the C 60 2– anions are similar within this group of compounds. However, there are no indications for significant deformations of the cages as a whole, which could be attributed to a Jahn‐Teller distortion.