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Struktur eines Blei(II)‐Komplexes mit verknüpften Monothioquadratationen als Liganden
Author(s) -
Plitzner Miriam,
Heinl Ulrich,
Mattes Rainer,
Fröhlich Roland
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200107)627:7<1426::aid-zaac1426>3.0.co;2-1
Subject(s) - crystal structure , chemistry , ligand (biochemistry) , crystallography , solid state , stereochemistry , ion , receptor , organic chemistry , biochemistry
A Lead(II) Complex with Linked Monothiosquarate Ions as Ligands The thiosquarate ligand bis‐1,2‐(2‐hydroxy‐3,4dione‐cyclobut‐1‐enylsulfanyl)‐ethane and its lead(II) complex have been prepared. According to the crystal structure analysis the complex has a unique layer structure in the solid state. The layers consist of a superposition of cyclic dimeric complexes and of chain like polymeric complexes. The shortest nonbonding Pb…Pb distances are 4.0 Å.