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Gallium Zigzag Chains as an Ordering Principle in η 5 ‐2,5‐di‐( t ‐butyl) phospholylgallium(I)
Author(s) -
Chojnacki Jaroslaw,
Baum Elke,
Krossing Ingo,
Carmichael Duncan,
Mathey Francois,
Schnöckel Hansgeorg
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200106)627:6<1209::aid-zaac1209>3.0.co;2-1
Subject(s) - zigzag , chemistry , crystallography , molecule , stereochemistry , gallium , solid state , organic chemistry , mathematics , geometry
The solid state structure of η 5 ‐2,5‐di‐( t ‐butyl)phospholylgallium(I) 1 was determined by X‐ray diffraction at 190 K. The molecules of 1 are partly organized in a for sandwich complexes new type of structure: a Ga zigzag chain in which the aromatic phospholyl rings alternate on both sides of the chain.