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Na 3 RuD 7 – Synthese und Struktur
Author(s) -
Bronger W.,
Sommer T.,
Swinder L.,
Müller P.
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200106)627:6<1113::aid-zaac1113>3.0.co;2-4
Subject(s) - ruthenium , crystallography , neutron diffraction , deuterium , hydrogen , chemistry , bar (unit) , polyhedron , materials science , crystal structure , physics , geometry , organic chemistry , nuclear physics , mathematics , meteorology , catalysis
Na 3 RuD 7 – Synthesis and Structure Na 3 RuD 7 was synthesized by the reaction of sodium deuteride with ruthenium powder under a hydrogen pressure of 6000 bar at 900 K. X‐ray investigations on powdered samples and elastic neutron diffraction experiments led to the atomic arrangement (space group: P 4 2 / mnm ), which is characterized by isolated [RuD 7 ]‐anions. The coordination polyhedron formed by the seven deuterium ligands can be described as a distorted pentagonal bipyramide.