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A Novel Alkene(alkyl)(aqua)(aryl)platinum(II) Complex – [Pt{CH(CH 2 C 6 F 5 )CH 2 CH 2 CH=CH 2 }(C 6 F 5 )(OH 2 )]
Author(s) -
Deacon Glen B.,
Drago Penny R.,
Göbbels Dirk,
Wickleder Mathias S.,
Meyer Gerd
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200105)627:5<811::aid-zaac811>3.0.co;2-a
Subject(s) - chemistry , aryl , platinum , medicinal chemistry , monoclinic crystal system , alkene , alkyl , ligand (biochemistry) , diene , double bond , crystal structure , stereochemistry , oxidative addition , crystallography , catalysis , polymer chemistry , organic chemistry , biochemistry , receptor , natural rubber
From the reaction of PtCl 2 (hex) (hex = hexa‐1,5‐diene) with LiC 6 F 5 in diethyl ether, the complex [Pt{CH(CH 2 C 6 F 5 )CH 2 CH 2 CH=CH 2 }(C 6 F 5 )(OH 2 )] ( 1 ) was isolated. The crystal structure (monoclinic, C 2/ c (no. 15), Z = 8, a = 15.241(3), b = 16.579(2), c = 16.225(2) Å, β = 111.12(2)°) shows a complex with square planar coordination around platinum with a template formed 1‐pentafluorophenylhex‐5‐en‐2‐yl ligand, and C 6 F 5 and aqua ligands trans to the double bond and alkyl carbon, respectively.