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Die Kristallstruktur von Bortriiodid, BI 3
Author(s) -
Albert Barbara,
Schmitt Konny
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200105)627:5<809::aid-zaac809>3.0.co;2-j
Subject(s) - triiodide , crystal structure , sublimation (psychology) , crystallography , rietveld refinement , boron , materials science , powder diffraction , chemistry , organic chemistry , psychology , electrode , dye sensitized solar cell , electrolyte , psychotherapist
Crystal Structure of Boron Triiodide, BI 3 Boron triiodide as a micro‐crystalline powder was obtained after sublimation of the reaction product of NaBH 4 and iodine. An X‐ray powder diagram of the temperature‐, air‐, and light‐sensitive compound was collected at –73 °C. According to the results of the Rietveld refinement, the crystal structure of BI 3 is isotypic to that of BCl 3 (space group P6 3 /m, no. 176, a = 699.09(2), c = 736.42(3) pm). The B–I bond length was determined to be 211.2(8) pm.