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trans ‐[Re(NH 3 )I 2 (Me 2 PhP) 3 ]I 3 – Bildung eines Amminaus einem Nitridoliganden
Author(s) -
SchmidtBrücken B.,
Abram U.
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200101)627:1<7::aid-zaac7>3.0.co;2-u
Subject(s) - dichloromethane , protonation , ligand (biochemistry) , chemistry , solvent , decomposition , medicinal chemistry , organic chemistry , biochemistry , ion , receptor
trans ‐[Re(NH 3 )I 2 (Me 2 PhP) 3 ]I 3 – Formation of an Ammine Ligand from a Nitrido Ligand The reaction of [ReNCl 2 (Me 2 PhP) 3 ] (Me 2 PhP = dimethylphenylphosphine) with Me 3 SiI in dichloromethane results in the formation of trans ‐[Re(NH 3 )I 2 (Me 2 PhP) 3 ]I 3 . The unusual protonation of a nitrido ligand is due to the partial decomposition of the solvent.