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Study on the Existence of Hydrogen Bonds in Ammonium Permanganate
Author(s) -
Kótai László,
Argay Gyula,
Holly Sándor,
Keszler Ágnes,
Pukánszky Béla,
Banerji Kalyan K.
Publication year - 2001
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200101)627:1<114::aid-zaac114>3.0.co;2-y
Subject(s) - ammonium perchlorate , hydrogen bond , chemistry , perchlorate , ammonium , crystallography , crystal structure , infrared spectroscopy , inorganic chemistry , molecule , ion , organic chemistry , combustion
The crystal structures of ammonium permanganate and ammonium perchlorate at 293 K were determined and compared. X‐ray and vibrational spectroscopic data confirmed the existence of weak hydrogen bonds in NH 4 MnO 4 . These hydrogen bonds proved to be slightly stronger than H‐bonds in ammonium perchlorate. Difference between the results of diffuse reflectance and KBr matrix pellet IR spectra of NH 4 MnO 4 has been explained.