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Darstellung und Kristallstruktur eines Ditelluridovanadium(IV)‐Komplexes: [(μ‐η 1 ‐Te 2 )(μ‐N t Bu) 2 V 2 Cp 2 ]
Author(s) -
Preuss F.,
Billen M.,
Tabellion F.,
Wolmershäuser G.
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200012)626:12<2446::aid-zaac2446>3.0.co;2-s
Subject(s) - tellurium , crystallography , crystal structure , chemistry , single crystal , ring (chemistry) , ligand (biochemistry) , inorganic chemistry , organic chemistry , biochemistry , receptor
Synthesis and Crystal Structure of a Ditelluridovanadium(IV) Complex: [(μ‐η 1 ‐Te 2 )(μ‐N t Bu) 2 V 2 Cp 2 ] [(μ‐η 1 ‐Te 2 )(μ‐N t Bu) 2 V 2 Cp 2 ] ( 2 ) is formed from [ t BuN = VCp(PMe 3 ) 2 ] ( 1 ) upon reaction with elemental tellurium. 1 and 2 are characterized by spectroscopic methods (MS; 1 H, 13 C, 51 V NMR), in addition 2 by single crystal X‐ray diffraction. The crystal structure indicates a folded cyclodivanadazen ring bridged by a bidentated ditellurido ligand, the first example of this structure type.