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Struktur von Hexafulminatocobaltat(III), [Co(CNO) 6 ] 3–
Author(s) -
Mayer Peter,
Ponikwar Walter,
Feldl Klaus,
Swoboda Peter,
Beck Wolfgang
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200010)626:10<2038::aid-zaac2038>3.0.co;2-d
Subject(s) - cobalt , octahedron , crystal structure , chemistry , crystallography , metal , ion , carbon fibers , stereochemistry , inorganic chemistry , materials science , organic chemistry , composite number , composite material
Pseudohalogeno Metal Compounds. LXXVII. Structure of Hexafulminatocobaltate(III), [Co(CNO) 6 ] 3– In the crystal of [AsPh 4 ] 3 [Co(CNO) 6 ] the hexafulminatocobaltate(III) anion forms an ideal octahedron with linear C≡N–O ligands and with relatively short cobalt‐carbon bonds (Co–C 191 pm). In the crystal the [AsPh 4 ] + cations “dilute” the energy rich anions.