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[Mo 2 (O 2 C–CH 3 ) 4 · 1 / 2 {(CH 2 ) 6 N 4 } · 1 / 2 CH 2 Cl 2 ] – ein Donor‐Akzeptor‐Komplex mit supramolekularer Struktur
Author(s) -
Ackermann Hartmut,
Weller Frank,
Stief Ronald,
Dehnicke Kurt
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200007)626:7<1496::aid-zaac1496>3.0.co;2-q
Subject(s) - dichloromethane , tetrahedron , crystallography , supramolecular chemistry , chemistry , lattice (music) , acceptor , crystal structure , stereochemistry , materials science , physics , condensed matter physics , organic chemistry , solvent , acoustics
[Mo 2 (O 2 C–CH 3 ) 4 · 1 / 2 {(CH 2 ) 6 N 4 } · 1 / 2 CH 2 Cl 2 ] – a Donor‐Acceptor Complex with Supramolecular Structure Yellow single crystals of [Mo 2 (O 2 C–CH 3 ) 4 · 1 / 2 {(CH 2 ) 6 N 4 } · 1 / 2 CH 2 Cl 2 ] ( 1 ) have been obtained by the reaction of the silylated phosphaneimine Me 3 SiNPEt 3 with [Mo 2 (O 2 C–CH 3 ) 4 ] in dichloromethane solution. 1 forms a three‐dimensional network with linear N–Mo:Mo–N and tetrahedral (CH 2 ) 6 N 4 Mo 4 moieties, which is topologically related with the PtS type. Space group P4 2 /nnm, Z = 4, lattice dimensions at –70 °C: a = b = 1121.7(1), c = 1395.0(3) pm, R 1 = 0.0413.