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Stabilisierung von M + ‐Ionen (M = In, Tl) durch Dibenzyldichlorogallat
Author(s) -
Kopp Mike R.,
Pauls Jochen,
Neumüller Bernhard
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(200007)626:7<1493::aid-zaac1493>3.0.co;2-7
Subject(s) - crystallography , ion , chemistry , organic chemistry
Stabilization of M + Ions (M = In, Tl) by Dibenzyldichlorogallate MCl reacts with (PhCH 2 ) 2 GaCl to give M[(PhCH 2 ) 2 GaCl 2 ] [M = In ( 1 ), Tl ( 2 )]. 1 and 2 were characterized by NMR, IR and MS techniques. In addition, an X‐ray structure determination of 1 was performed. According to this, 1 consists of four‐membered In 2 Cl 2 rings connected by weak In…Cl contacts (344 pm) along [010] to a coordination polymer. The In + ion is coordinated by four In–Cl and two In‐aryl interactions.