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Kristallstruktur von BaGdCl 5
Author(s) -
Masselmann Sönke,
Meyer Gerd
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/1521-3749(199803)624:3<357::aid-zaac357>3.0.co;2-v
Subject(s) - monoclinic crystal system , crystallography , crystal structure , group (periodic table) , materials science , chemistry , organic chemistry
Crystal Structure of BaGdCl 5 Colourless single crystals of BaGdCl 5 are obtained from a 1 : 2 molar mixture of BaCl 2 and GdCl 3 . It crystallizes with the monoclinic space group C2/c with a = 552.1(2), b = 1925.7(5), c = 687.4(2) pm, β = 93.25(4)° in a new structure. Ba 2+ and Gd 3+ have coordination numbers of 8 + 2 and 8, respectively.