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From 6‐ t ‐butylfulvene to highly functionalized five‐membered rings
Author(s) -
Baumgartner Judith,
Weber Hansjörg
Publication year - 2001
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/1520-636x(2001)13:3<159::aid-chir1014>3.0.co;2-o
Subject(s) - chemistry , stereochemistry , nanotechnology , materials science
6‐ t ‐Butylfulvene was used as the starting material for asymmetric dihydroxylation. The obtained protected diol ( 2 ) was used for several stereoselective functionalizations such as epoxidations, hydroboration, and aminohydroxylation. However, these fulvene derivatives proved to be rather unreactive and gave no conversion under, e.g., palladium (0), catalyses or hydroboration conditions. Chirality 13:159–163, 2001. © 2001 Wiley‐Liss, Inc.