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Controlled Orientation of Individual Molecules by Electrode Potentials
Author(s) -
Wan LiJun,
Noda Hiroyuki,
Wang Chen,
Bai ChunLi,
Osawa Masatoshi
Publication year - 2001
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/1439-7641(20011015)2:10<617::aid-cphc617>3.0.co;2-f
Subject(s) - orientation (vector space) , molecule , electrode , electrolyte , chemical physics , bipyridine , chemistry , materials science , nanotechnology , crystallography , organic chemistry , geometry , crystal structure , mathematics
Information storage flips molecules out : The orientation of individual molecules—vertically or horizontally on a Cu(111) surface—can be controlled in an electrolyte solution by application of an electrode potential. The transition is completely potential dependent, reversible and stable; such are the minimum requirements for computer memory devices. STM images show two orientations of an adlayer of 2,2′‐bipyridine (see graphic).

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