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Facile Syntheses of [8,9‐ 2 H 2 ]‐ and [8‐ 2 H]‐digeranyl
Author(s) -
Nakagawa Osamu,
Shimoda Kei,
Izumi Shunsuke,
Hirata Toshifumi
Publication year - 2000
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/1099-1344(200011)43:13<1301::aid-jlcr421>3.0.co;2-h
Subject(s) - chemistry , geraniol , organic chemistry , condensation , stereochemistry , chromatography , essential oil , thermodynamics , physics
[8,9‐ 2 H 2 ]‐ and [8‐ 2 H]‐(2 E ,6 E ,10 E ,14 E )‐2,6,11,15‐tetramethyl‐2,6,10,14‐hexadecatetraene (digeranyl) ( 1 and 2 ) have been synthesized from geraniol by the condensation of geranyl p ‐tolylsulfone and reductive desulfonylation in the key steps. Copyright © 2000 John Wiley & Sons, Ltd.