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Solid fuel burning in steady, strained, premixed flow fields: the graphite/air/methane system
Author(s) -
Egolfopoulos Fokion N.
Publication year - 2000
Publication title -
international journal of energy research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.808
H-Index - 95
eISSN - 1099-114X
pISSN - 0363-907X
DOI - 10.1002/1099-114x(200011)24:14<1257::aid-er655>3.0.co;2-n
Subject(s) - graphite , methane , nox , laminar flow , chemistry , thermodynamics , analytical chemistry (journal) , materials science , combustion , organic chemistry , physics
A detailed numerical investigation was conducted on the simultaneous burning of laminar premixed CH 4 /air flames and solid graphite in a stagnation flow configuration. The graphite and methane were chosen for this model, given that they are practical fuels and their chemical kinetics are considered as the most reliable ones among solid and hydrocarbon fuels, respectively. The simulation was performed by solving the quasi‐one‐dimensional equations of mass, momentum, energy, and species. The GRI 2.1 scheme was used for the gas‐phase kinetics, while the heterogeneous kinetics were described by a six‐step mechanism including stable and radical species. The effects of the graphite surface temperature, the gas‐phase equivalence ratio, and the aerodynamic strain rate on the graphite burning rate and NO x production and destruction mechanisms were assessed. Results indicate that as the graphite temperature increases, its burning rate as well as the NO x concentration increase. Furthermore, it was found that by increasing the strain rate, the graphite burning rate increases as a result of the augmented supply of the gas‐phase reactants towards the surface, while the NO x concentration decreases as a result of the reduced residence time. The effect of the equivalence ratio on both the graphite burning rate and NO x concentration was found to be non‐monotonic and strongly dependent on the graphite temperature. Comparisons between results obtained for a graphite and a chemically inert surface revealed that the chemical activity of the graphite surface can result in the reduction of NO through reactions of the CH 3 , CH 2 , CH, and N radicals with NO. Copyright © 2000 John Wiley & Sons, Ltd.