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Characterization of Ru(bpy) 2 (CO)(COO) prepared by CO 2 addition to Ru(bpy) 2 (CO) in acetonitrile
Author(s) -
Fujita Etsuko,
Chou Mei,
Tanaka Koji
Publication year - 2000
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/1099-0739(200012)14:12<844::aid-aoc76>3.0.co;2-g
Subject(s) - chemistry , acetonitrile , carboxylate , solvent , characterization (materials science) , ruthenium , inorganic chemistry , medicinal chemistry , stereochemistry , catalysis , organic chemistry , nanotechnology , materials science
A carboxylate complex, [Ru(bpy) 2 (CO)(COO)], was prepared by the addition of CO 2 to the doubly reduced species, [Ru I (bpy)(bpy −. )(CO)], in CH 3 CN. The IR and UV–vis spectra of [Ru(bpy) 2 (CO)(COO)] show a marked cation and solvent dependence. Copyright © 2000 John Wiley & Sons, Ltd.