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Cyclopalladation of Schiff base ligands: crystal and molecular structures of [Pd‐ { 2,4‐(OCH 3 ) 2 C 6 H 2 C(H) N (C 6 H 11 )‐ C 6 , N } (µ‐O 2 CCH 3 )] 2 and [Pd‐ {3,4‐(OCH 3 ) 2 C 6 H 2 C(H) N(C 6 H 11 )‐ C 6 , N } (µ‐O 2 CCH 3 ] 2
Author(s) -
Mosteiro Roberto,
Perille Elena,
Fernández Alberto,
LópezTorres Margarita,
Vila José M.,
Suárez Antonio,
Ortigueira Juan M.,
Pereira M. Teresa,
Fernández Jesús J.
Publication year - 2000
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/1099-0739(200010)14:10<634::aid-aoc50>3.0.co;2-8
Subject(s) - chemistry , schiff base , crystal structure , palladium , stereochemistry , crystallography , catalysis , biochemistry
X‐ray diffraction studies show that the title cyclometallated compounds show each palladium atom C,N ‐bonded to a deprotonated Schiff base ligand. The molecular configuration is a dimeric form of the anti isomer with the cyclopalladated moieites in an ‘open‐book’ arrangement linked by two acetate bridging ligands. Copyright © 2000 John Wiley & Sons, Ltd.