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Silicometallics and catalysis
Author(s) -
Marciniec Bogdan
Publication year - 2000
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/1099-0739(200010)14:10<527::aid-aoc35>3.0.co;2-x
Subject(s) - chemistry , catalysis , combinatorial chemistry , organic chemistry
Several processes of silicon substrates (such as hydrosilylation, dehydrogenative silylation and double silylation of alkenes and alkynes, silylative coupling versus cross‐metathesis of vinylsilanes with alkenes, polycondensation of divinyl‐substituted silicon compounds versus ADMET polymerization, dehydrocoupling of hydrosilanes and silylformylation of acetylene) by transition‐metal complexes are briefly overviewed. All the reactions occur via a mechanism involving intermediates containing metal–silicon (i.e. silicometallics versus organometallics) and metal–hydrogen bonds, only occasionally accompanied (sided) by intermediates including metal–carbon bonds. Copyright © 2000 John Wiley & Sons, Ltd.