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Sandwich and half‐sandwich complexes derived from pentamethylcyclopentadienyl tetracarbonyl vanadium, Cp*V(CO) 4
Author(s) -
Herberhold Max,
Dietel Anna Maria,
Peukert Jürgen,
Pfeifer Andreas,
Milius Wolfgang
Publication year - 2000
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/1099-0739(200010)14:10<519::aid-aoc34>3.0.co;2-0
Subject(s) - chemistry , decarbonylation , vanadium , oxidation state , ligand (biochemistry) , diamagnetism , medicinal chemistry , nuclear magnetic resonance spectroscopy , stereochemistry , inorganic chemistry , polymer chemistry , organic chemistry , catalysis , biochemistry , physics , receptor , quantum mechanics , magnetic field
A survey is presented on various reactions of Cp*V(CO) 4 , including CO ligand substitution and/or oxidative decarbonylation, to give complexes in which the formal oxidation state of vanadium may vary from 0 to V. Diamagnetic Cp*V complexes can be rapidly and conveniently characterized by 51 V NMR spectroscopy. Copyright © 2000 John Wiley & Sons, Ltd.