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Selective determination of alkylmercury compounds in solid matrices after subcritical water extraction, followed by solid‐phase microextraction and GC–MS
Author(s) -
Beichert Andreas,
Padberg Susanne,
Wenclawiak Bernd W.
Publication year - 2000
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/1099-0739(200009)14:9<493::aid-aoc15>3.0.co;2-r
Subject(s) - solid phase microextraction , chemistry , derivatization , extraction (chemistry) , chromatography , thermal desorption , solid phase extraction , gas chromatography–mass spectrometry , aqueous solution , gas chromatography , desorption , mass spectrometry , adsorption , organic chemistry
A method for the extraction and determination of methylmercury (MeHg) in solid matrices is presented. Combining the advantages of two extraction techniques—subcritical water extraction (subWE) and solid‐phase microextraction (SPME)—selective separation of MeHg from soils is possible. The procedure is based on extraction with subcritical water without using organic solvents, followed by in situ aqueous‐phase derivatization with sodium tetraethylborate and headspace SPME with a silica fiber coated with poly(dimethylsiloxane). The optimization of the extraction parameters is described. The identification and quantification of the extracted alkylmercury compounds from spiked soil samples is performed by GC–MS after thermal desorption. Copyright © 2000 John Wiley & Sons, Ltd.