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Synthesis of a Linear Assembly Consisting of a Central Ru(Phen) 3 2+ Derivative and Two Peripheral Porphyrins
Author(s) -
SalomRoig Xavier J.,
Chambron JeanClaude,
Goze Christine,
Heitz Valérie,
Sauvage JeanPierre
Publication year - 2002
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200210)2002:19<3276::aid-ejoc3276>3.0.co;2-r
Subject(s) - chemistry , ruthenium , ligand (biochemistry) , phenanthroline , stereochemistry , derivative (finance) , zinc , metal , molecule , crystallography , organic chemistry , receptor , catalysis , financial economics , economics , biochemistry
A ruthenium( II ) precursor complex containing a bis‐phenanthroline ligand, leading to a controlled helical structure around the metal centre, and a third phenanthroline‐type ligand has been prepared. The spatial arrangement of the system is such that two chemical groups are disposed trans to one another on an axis running through the Ru centre. By appropriate functional group transformation, these two groups can be attached to monosubstituted zinc( II ) porphyrins (PZn) to afford a linear array consisting of a central ruthenium( II ) complex and two peripheral PZn motifs. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)