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An Easy Route to 2‐Amino‐β‐ C ‐Glycosides by Conjugate Addition to 2‐Nitroglycals
Author(s) -
Pachamuthu Kandasamy,
Gupta Anuradha,
Das Jagattaran,
Schmidt Richard R.,
Vankar Yashwant D.
Publication year - 2002
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200205)2002:9<1479::aid-ejoc1479>3.0.co;2-p
Subject(s) - conjugate , chemistry , carbanion , adduct , bicyclic molecule , glycoside , michael reaction , stereochemistry , addition reaction , organic chemistry , catalysis , mathematical analysis , mathematics
2‐Nitroglycals were found to undergo conjugate addition with a variety of stabilized soft carbanions. The Michael adducts from galactal derivatives were converted into bicyclic lactams. (© Wiley‐VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)