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Unsaturated Carbanions, Heterocumulenes and Thiocarbonyl Compounds − New Routes to Heterocycles
Author(s) -
Brandsma Lambert
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200112)2001:24<4569::aid-ejoc4569>3.0.co;2-w
Subject(s) - chemistry , carbanion , carbon disulfide , organic chemistry , disulfide bond , medicinal chemistry , biochemistry
The combination of metallated unsaturated compounds and heterocumulenes or thiocarbonyl compounds offers several possibilities for further reactions, especially those producing heterocyclic systems. This review covers research in this field carried out in the author’s group at Utrecht University over the past two decades. The starting compounds involved in these investigations are mainly olefinic, acetylenic and allenic derivatives, isothiocyanates, carbon disulfide and some non‐enethiolisable thiocarbonyl compounds.