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Pd/Ag‐Catalyzed Direct Coupling of 1‐Trimethylsilyl Alkynes with Vinyl Triflates
Author(s) -
Bertus Philippe,
Halbes Ulla,
Pale Patrick
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200112)2001:23<4391::aid-ejoc4391>3.0.co;2-d
Subject(s) - chemistry , catalysis , palladium , tetrabutylammonium fluoride , trimethylsilyl , iodide , coupling (piping) , fluoride , halide , polymer chemistry , organic chemistry , inorganic chemistry , metallurgy , materials science
The commercially available tetrabutylammonium fluoride trihydrate is able to promote the cross‐coupling of vinyl triflates with 1‐trimethylsilylalkynes in the presence of a catalytic amount of tetrakis(triphenylphosphane)palladium and silver iodide.