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trans ‐[PtCl 2 (Am)(C 2 H 4 )] and [PtCl 3 (C 2 H 4 )] − [AmH] + , Containing Binaphthyl Secondary Amines − Efficient Chiral Derivatizing Agents for the Enantiodiscrimination of Chiral Olefins by 195 Pt NMR Spectroscopy
Author(s) -
UccelloBarretta Gloria,
Bernardini Raffaella,
Balzano Federica,
Venturelli Francesca,
Caporusso Anna Maria,
Salvadori Piero
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200110)2001:19<3651::aid-ejoc3651>3.0.co;2-4
Subject(s) - chemistry , amine gas treating , nuclear magnetic resonance spectroscopy , azepine , diastereomer , stereochemistry , spectroscopy , medicinal chemistry , organic chemistry , physics , quantum mechanics
The complexes [PtCl 3 (C 2 H 4 )] − [AmH] + and trans ‐[PtCl 2 (Am)(C 2 H 4 )], containing the binaphthyl secondary amine ( S )‐3,5‐dihydro‐4 H ‐dinaphth[2,1‐ c :1′,2′‐ e ]azepine, are efficient and versatile CDAs for the enantiodicrimination of simple olefins by 195 Pt NMR analysis of their diastereoisomeric derivatives.