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Electrochemical Selective Incorporation of CO 2 into Terminal Alkynes and Diynes
Author(s) -
Köster Frank,
Dinjus Erkhardt,
Duñach Elisabet
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200109)2001:18<3575::aid-ejoc3575>3.0.co;2-e
Subject(s) - chemistry , electrochemistry , terminal (telecommunication) , anode , magnesium , cathode , combinatorial chemistry , organic chemistry , electrode , telecommunications , computer science
Electrochemical incorporation of CO 2 into terminal alkynes and diynes on silver cathodes occurred selectively, to afford monocarboxylic acid derivatives in good yields. The electrolyses were carried out in one‐compartment cells fitted with magnesium anodes, under mild conditions.