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Reaction of 1,2,4,5‐Tetramethyl‐1,4‐cyclohexadiene with Ozone − Competition between Oxidative Cleavage and Oxydehydrogenation
Author(s) -
Jung In Chan
Publication year - 2001
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/1099-0690(200105)2001:10<1899::aid-ejoc1899>3.0.co;2-l
Subject(s) - chemistry , ozonolysis , dehydrogenation , oxidative cleavage , ozone , epoxide , cleavage (geology) , oxidative phosphorylation , pentane , organic chemistry , bond cleavage , medicinal chemistry , photochemistry , catalysis , biochemistry , geotechnical engineering , fracture (geology) , engineering
Treatment of 1,2,4,5‐tetramethyl‐1,4‐cyclohexadiene ( 1 ) on polyethylene and in pentane with excess ozone afforded mixtures of the oxydehydrogenation product 2 and of the oxidative cleavage product 4 in ratios of 0.5:1 and 19:1, respecively. Epoxidation of 1 followed by ozonolysis of the epoxide 6 provided the epoxyozonide 7 .